ANHYDROUS HYDRAZINE
Physical Properties:

 

Melting point: 1.4℃                  Boiling point: 113.5℃

Saturated vapour pressure: 1.92/25℃ Kpa

Relative density(water = 1): 1.01    Relative density(air = 1): 1.11

Solubility: Dissolved in water, alcohol, liquid ammonia and organic

solvents

Critical temperature: 380℃            Critical pressure: 14.69Mpa

Heat of combustion: 621.1kj/mol

 

Chemical Properties:

 

Combustibility: flammable         Fire insurance grade: second

Flash point: 38℃                 Spontaneous combustion temperature: 270℃

Explosive limit(v%): 2.9 min. --- 98.0max.

Dangerous characters: the product has strong restorative ability. 

 

Contacted with flame:

Heat can cause burning and explosion.Contacted with oxidizers such as

Chromium acid anhydride, KClO3, KMnO4 etc. can cause strong chemical

reaction and burning or explosion. Its vapour is hazardous. If be ignited, the product can burn without oxygen. If be heated, it decomposed into toxic nitro oxide gas.

 

Combustion (decomposition) product: nitro oxide (NO)

Stability: Unstable                Polymerization: none

Avoid: strong oxidizer, oxygen, copper etc.

Storage condition: avoid heat and direct sunshine

Fire extinguishing methods: using atomized water, carbon dioxide, foam, dry powder and sand etc. as fire extinguishing agent.

 

Dangerous Class:

Toxicity: middling

        LD50: 60mg/kg (adult rat swallow); 91mg/kg (rabbit skin contact)

        LC50: 570ppm 4 hours (adult rat inhalation)

 

UN NO.2029                      CAS NO.302-01-2
Emergency:disperse the population in polluted area to safe place, cut off fire sources. Advise the treating people wear pressure self respirator and anti-chemicals clothing. Don’t contact the leaked product directly. Spray water can lower vaporization, but can not lower the flammability. Absorb with sand or other inflammable materials, transported to suitable place for treating. It can wash away by large quantity water, diluted water released to effluent water system.  
 

MONOMETHYL HYDRAZINE

Physical Properties

 

Freezing point: -52.5℃                  Boiling point: 87.8℃

Saturated vapour pressure: 6.61/25℃ Kpa

Relative density(water = 1): 0.87    Relative density(air = 1): 1.6

Solubility: Dissolved in water, alcohol, liquid ammonia and organic

solvents

Critical temperature: 235℃     

 

Chemical Properties

 

Combustibility: flammable       Fire insurance grade: second

Flash point: -8℃               Spontaneous combustion temperature: 194℃

Explosive limit(v%): 2.5 min. --- 98.0max.

Dangerous characters: the product has strong restorative ability. 

 

Contacted with flame:

Heat can cause burning and explosion.Contacted with oxidizers such as

Chromium acid anhydride, KClO3, KMnO4 etc. can cause strong chemical

reaction and burning or explosion. Its vapour is hazardous. If be ignited, the product can burn without oxygen.

 

Combustion (decomposition) product: nitro oxide (NO)

Stability: Unstable                Polymerization: none

Avoid: strong oxidizer, oxygen, copper etc.

Storage condition: Space in container of its vapor phase must fill with nitrogen in storage.

Fire extinguishing methods: using atomized water, carbon dioxide, foam, dry powder and sand etc. as fire extinguishing agent.

 

UN NO.1244                      CAS NO.60-34-4
Emergency:disperse the population in polluted area to safe place, cut off fire sources. Advise the treating people wear pressure self respirator and anti-chemicals clothing. Don’t contact the leaked product directly. Spray water can lower vaporization, but can not lower the flammability. Absorb with sand or other inflammable materials, transported to suitable place for treating. It can wash away by large quantity water, diluted water released to effluent water system.  
 

UNS-DIMETHYL HYDRAZINE

Physical Properties

 

Freezing point: -57.2℃                  Boiling point: 63.3℃

Saturated vapour pressure: 20.9/25℃ Kpa

Relative density(water = 1): 0.78    Relative density(air = 1): 1.94

Solubility: Dissolved in water,alcohol,hydrazine,petrol etc.

Critical temperature: 247.8℃   

 

Chemical Properties

 

A mildly alkaline and a very strong reducing agent

Combustibility: flammable       Fire insurance grade:

Flash point: -15℃             

Explosive limit(v%): 2.0 min. --- 95.0max.

 

UN NO.1163                      CAS NO.57-14-7
Emergency::disperse the population in polluted area to safe place, cut off fire sources. Advise the treating people wear pressure self respirator and anti-chemicals clothing. Don’t contact the leaked product directly. Spray water can lower vaporization, but can not lower the flammability. Absorb with sand or other inflammable materials, transported to suitable place for treating. It can wash away by large quantity water, diluted water released to effluent water system.  
 

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